Fig. 5 a) SPLS-1 scheme, b) SPLS-2 scheme and c) SPLS-3 scheme. ) 2-azidoethyl B-N-acetyl-galactosamine, dry pyridine; ) PPh3, dry CH2Cl2; ) 10% H2O/THF; ) succinic anhydride, DIEA, DMF; ) H-glu(O-dodecyl)2, DPPA, DIEA, DMF; ) 2% TFA/CH2Cl2; ) H-glu(O-allyl)2, DPPA, DIEA, DMF; ) Pd (OAc)2, PPh3, morpholine, THF; ) n-hexanol, HOBt, DMAP, DIC, DMF.
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